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								|  | «  on: September 28, 2009, 03:22:09 PM » |  | 
 
 
October 2009: Pigment vs Dye Today
 Background 
        Competing technology always 
        has a way of equalizing differences.  Five years ago, LCD 
        televisions were taking a back seat to the competing plasma market.  
        LCD TV's, while they delivered a decent bright picture, suffered from 
        poor blacks and shifting colors when viewed at an angle.  Plasma 
        TV's delivered superb blacks and a wider color range, especially when 
        viewed in dim lighting but they struggled a bit in bright rooms as they 
        were not as bright as LCD TV's.  Of course, manufacturers always 
        work on weaknesses to mitigate or eliminate them.  Now LCD TV's 
        have LED backlighting, a broader color range, and they look as good as 
        plasmas from an angle.  On the other side of the fence, plasmas 
        have gotten brighter and more usable in places other than dark rooms.  
        The technology is meeting in the middle. Is the same happening with pigment versus dye printers?  
        Five years ago, you could print a photo on 
        a dye based printer and with some printers, inks, and papers, you could 
        almost watch the ink fade if you left the print in open air on your 
        desk.  Some combinations (of ink and paper) were so bad that the 
        print would be almost unrecognizable if left on a desk in a bright room 
        for a month or two.  At the same time, pigment based printers were 
        starting to make it to the mainstream but they had some significant 
        issues as well.  While their prints lasted much longer than dye 
        based prints, they had significant issues with metamerism (colors 
        looking different under different lighting) and anyone who was truly 
        honest would admit that the pigment printers simply could not produce a 
        good glossy print. Where are things today?  Have the two 
        technologies met in the middle somewhere?  Do you still have to get 
        a pigment ink printer if you want longevity?  Let's take a look at 
        how far we've come in the last ~5 years.   Dye Based Inks 
        Inkjet printers have 
        traditionally printed with dyes that basically soak into the paper and 
        dye the paper fibers.  Dye based inks are easier to make and easier 
        to deliver to the paper so they are generally cheaper.  Of course, 
        it didn't take very long for people to realize that their inkjet prints, 
        while they looked as good as real photographs when they came out of the 
        printer, faded faster than traditional photos.  At this point there 
        was a split in technology.  One branch went for a more stable ink 
        base (pigment inks) while the other focused on getting better longevity 
        out of the existing dye based inks.  Dye based inks generally have 
        a broader color gamut, meaning that they can deliver a wider range of 
        bright colors compared to pigment inks.  In addition, the colors 
        produced by dye inks don't tend to shift under different lighting.  
         Working with these pros in 
        mind, manufacturers set out to mitigate some of the longevity issues 
        with dye based inks.  The result is better inks and better paper, 
        both of which lend themselves to long lasting dye based prints.   Pigment Based Inks 
        Pigment based inks started 
        to become popular with the Epson 2200 about six years ago.  Pigment 
        inks then boasted longevity that far exceeded that of traditional 
        photographs and some started calling pigment based printers "archival".  
        While the longevity was impressive, it was clear that there were some 
        significant problems with pigment technology out of the gate.  
        Prints just didn't have the vibrance of dye inks so photos often looked 
        a bit dull.  In addition, no one could seem to get a true glossy 
        print on glossy paper.  When you tried, you might get some gloss in 
        some places on the print while other areas looked like a matte surface.  
        This "gloss differential" kept people away from the glossy papers when 
        using pigment inks at first.  Finally, pigment inks tended to shift 
        color under different lighting so while skin tones might look fine in 
        your office, they might turn green under a different light source. Again, working from the 
        positive aspect of longevity, manufacturers set out to mitigate or 
        eliminate the above tradeoffs.  What we now have are pigment inks 
        with a broader color gamut, less tendency to color shift under different 
        lighting, and special "gloss optimizer" inks that work around the 
        problem of low gloss.  Papers have advanced well too, with some 
        tailoring to the dye inks and others tailoring to pigment inks.  
        Pick the right paper for the ink you are using, and you can't go wrong.  
        Now we can print beautiful glossy photos from pigment printers and still 
        enjoy better longevity.   Meeting in the middle 
        So how far has each 
        technology advanced?  Have they met in the middle and is it a close 
        race like LCD and plasma TV's?  Unfortunately it is very difficult 
        to test and back up your findings when evaluating ink and paper 
        permanence.  Wilhelm 
        Research is the leader in this type of testing and you can check out 
        their web site.  While much has been done to improve both dye and 
        pigment ink technology and they are on their way to a meeting in the 
        middle, it's not quite an equal race yet.  Turns out the drawbacks 
        of pigment inks were a little easier to mitigate and/or a little less 
        noticeable to viewers.  Right now, I'd have to still give the edge 
        to pigment based printers when considering print longevity and quality 
        on the same page.  Dye based printers have made great strides and 
        with newer dye ink formulations such as Canon's
        
        Chromalife 100 inks, dye printers are now producing prints that last 
        as long or longer than traditional photos.  It seems many want more 
        than that though!  Even with ink reformulations and better papers, 
        pigment based prints still last two to three times longer than dye based 
        prints. And yes, there are still 
        drawbacks on both sides.  All of the same issues still exist just 
        to a much lesser degree, so instead of a wide gap between quality and 
        longevity, the gap is closing.  Do you base your printer purchase 
        on "accelerated testing" that indicates today's dye based prints will 
        only last 30 years displayed behind glass compared to 100 years for 
        pigment inks?  That's up to you, but the reality here is that no 
        print is going to last forever and if you really want "permanence", 
        you'd have to find some form of media that doesn't degrade with time: 
        something that is easier said than done and would take another full 
        article to cover! My own personal feeling is 
        that there is room for both dye and pigment ink printing.  Pigment 
        printers still can't quite produce the "wet" quality of gloss prints 
        from a dye printer so if that's what you are looking for, there's 
        nothing wrong with sacrificing a bit of longevity for better gloss.  
        As with many things, we pick what is best for what we do.  If you 
        primarily make big prints to hang on a wall for your own pleasure, a dye 
        based printer may prove to be cheaper and more effective.  If you 
        are creating photo albums that you want to last generations, a pigment 
        printer may be a better choice.  Suffice it to say that both dye 
        and pigment ink printers have their place and it is no longer sensible 
        to buy into either technology on the basis of longevity alone. 
           Summary 
        Hopefully this article has 
        shed some light on where we stand today with dye based inkjet printers 
        versus pigment based inkjet printers.  The bottom line is that both 
        technologies are in the typical race to meet in the middle where their 
        disadvantages are mitigated to the point that picking between the two 
        technologies will eventually be a matter of personal preference.  I 
        believe both dye and pigment printers are here to stay and they will 
        only get better.  As a reality check, however, it is important to 
        point out that there is no such thing as "permanence" when it comes to 
        printed photographs.  The only real way to ensure long lasting 
        photos is to archive your photos to some media and then keep updating 
        that media to current standards while at the same time reprinting any 
        photographs that may have faded.  Since few of us have the time or 
        resources to reprint entire photo albums, I believe pigment printing is 
        a good choice for scrapbooking or important albums that need to last as 
        long as possible.  Larger "gallery" prints and prints that get 
        swapped out from time to time should be fine for many years printed with 
        dye inks and may have a little more "punch" than the pigment prints 
        while they are on display.  If the current 30 years behind glass 
        and 100 years in a closed album is not enough for what you have in mind, 
        you can double or triple that with a pigment ink printer.  The 
        choice is yours.   Mike Chaney |  
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						| Seth | 
								|  | « Reply #1 on: September 28, 2009, 07:04:57 PM » |  | 
 
 The dye-based side certainly has advanced.  It doesn't even pay to have the small prints done on silver-dye photographic process becausethewy won't last as long.
 I use Picturemates for that type of work.  At less than $0.25/print it's not worth the time to take them out.  The Wilhelm ratings you talk about have these Epsons even higher: 100 years under glass and >200 years in an album.  Not much else to ask for there.
 
 It seems the only thing holding back a full pigment gloss print is the black.  (I am basing the statement on Epson 2200/2400 and other K3 printers.)  Once they get a pigment black that won't rub off the gloss print, the PK/MK necessity will fade (pun intended).
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 Seth<CWO4 (FMF) USN, Ret.>
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						| Fred A | 
								|  | « Reply #3 on: September 28, 2009, 10:16:43 PM » |  | 
 
 The dye-based side certainly has advanced I see no one even groaned at my last post, so I will respond on a more sober note. There is a certain shade of red, not any odd mix, but a nice rich red. It's the Qimage opening logo and the same again when you click HELP and ABOUT in Qimage. It's a nice rich red. My R1800 cannot  reproduce that shade (pigment ink) The Canon printer that still has Dye ink makes a perfect match. My old 1280 (dye ink) could match too. So I can be an advocate for a new Dye ink printer when the R 1800 decides to go to Printer Heaven. Glad to learn from Mike's article that Dye ink printers were not kicked to the curb. Fred |  
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						| LindaJ 
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								Posts: 13
								
								
								
								
								
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								|  | « Reply #4 on: September 29, 2009, 02:28:21 AM » |  | 
 
 Because of all the things discussed in Mike's article, I have a dye printer (Epson Artisan 700 with Claria inks), and an Epson R2400 which has pigments. I avoided the dye printers until the Claria inks came out. I'm a happy camper.    The Artisan is wireless which particularly appealed to me since I don't have to tether it to the pc. I also have a Picturemate which is a nice little machine. Nice article, Mike. Linda J |  
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						| Seth | 
								|  | « Reply #5 on: September 29, 2009, 03:43:20 PM » |  | 
 
 There is a certain shade of red, not any odd mix, but a nice rich red. It's the Qimage opening logo and the same again when you click HELP and ABOUT in Qimage. It's a nice rich red.[/quote] Fred- WHICH red?  There are hundeds (thousands?) in there.  Everything from 231-0-0, 255-2-2 to darks in the 148-0-0, 140-0-8 range.  Some shades show as out of gamut.  Just too many variables trying to print Mike's creation (or somebody he hired).  There is a lot of deep orange that I see. In favor of your 1800, it usually reviewed having exceptionally accurate reds; it was lacking (but adjustable) in the yellows output.  Head alignment can do a subtle change without causing visible lines. It may not be a dye vs. pigment issue at all.  Ultrachrome Hi-gloss is "pigment-based;" it has dyes also. Don't fret. The non-reproducable sRGB QI logo is indicitive of the non-reproducable printing ability of QI.             |  
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 Seth<CWO4 (FMF) USN, Ret.>
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						| Fred A | 
								|  | « Reply #6 on: September 29, 2009, 03:49:35 PM » |  | 
 
 WHICH red This red.  It's the Qimage opening logo and the same again when you click HELP and ABOUT in Qimage. You must get and open Qimage to see it.         |  
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						| Fred A | 
								|  | « Reply #7 on: September 29, 2009, 04:07:44 PM » |  | 
 
 I should clarify....That test where the red from the R1800 was not as good as the Canon, was printed on sort of a decent quality matte surface Neato CD label, using Surething as the app for the printing. Tried VIVID on off, increased saturation, played with the colors, just couldn't make it happen.
 
 Fred
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						| Seth | 
								|  | « Reply #8 on: September 29, 2009, 04:21:59 PM » |  | 
 
 I should clarify....That test where the red from the R1800 was not as good as the Canon, was printed on sort of a decent quality matte surface Neato CD label, using Surething as the app for the printing. Tried VIVID on off, increased saturation, played with the colors, just couldn't make it happen.
 
 Ahhhh.  You answered your own problem.  Neato and CD label.  I don't think one would ever get "true" colors.  Who knows the coating and how would you profile it? Surely you are not putting paper labels on CDs in this day and age.      That can be deadly.  The R1800 prints direct to CDs.  Although I do not print labels on CDs, I use injet-printable media because of the extra coating.  It's safer when writing on them. |  
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						| Fred A | 
								|  | « Reply #9 on: September 29, 2009, 05:00:48 PM » |  | 
 
 yes it is sort of NON color management, but under the same conditions, the Canon gets there. The canon has the old dye inks     Fred |  
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						| Ernst Dinkla | 
								|  | « Reply #10 on: September 30, 2009, 09:01:54 AM » |  | 
 
 Mike, The summary surprises me.  I can agree with most remarks in the article till the summary. Though metamerism with dye inks is quite common too, not the least because the dye printers are 4 or 6 channel models without extra grey inks. Not to mention the OBA content of all longer lasting dye ink compatible papers. The industry more or less advises the split: (long lasting) dye for albums, pigment for display. Going against the grain of that advice will be difficult as sketched below. In practice people tend to have one printer that does all and they have to cope with the limitations of one system. With the split between dye inks for display and pigment inks for albums you run into many practical problems too.  If you would like to have a matte paper in your frame with glass at the front then dye + matte papers is the worst combination for aging, the compatible papers for the longer lasting dye inks of the big three are all satin or gloss. All with a PVA or gelatine inkjet coating that embeds the dye and protects it more against gas fading. Without glass the prints will face more gas fading and dyes are less UV light resistent. The compatible papers all have OBA content which grays/yellows the paper white fast if displayed unprotected, gas fading is again the usual cause as the OBAs are dyes as well. Overall color shifts can happen fast, including skin colors going all the way. Dye ink prints in albums have a considerably longer archivability than when they are on display. They can be used with compatible satin or gloss papers that give a good gamut and contrast which is nice the way they are used. Gloss differential and bronzing are almost non existent with dye inks on gloss papers. Pigment inks can be used succesfully on matte papers. They have better visible- and UV light resistance. The gamut is now at the same level or better  if compared to 6 channel dye inks. On some printers the gloss enhancer allows equally good gloss and satin printing and the prints made that way survive indoor display without glass for much longer times. Papers with low OBA content exist for pigment inks. There are hardly any dye based wide formats anymore. So whether you like it or not above A3+ it will be pigment mainly. Few excepions, the HP DJ 130 etc. The split between dye and pigment inks is less hard than it seems. Pigment particles are very related to the dye inks around and are more or less rolled up dye molecules, the best pigment inks  have each particle coated with a protective transparant polymer coating that is more or less gel like to give better gloss, a better bond and better penetration of the inkjet coating on papers. Dyes like the longer lasting Epson Claria are hybrids in between dye and pigment, early Epson documents had several hints to pigment while it is officialy declared a dye ink. The Wilhelm test results for that ink correspond to that hybrid status. I would recommend Aardenburg as the better test institute. The method is better, the business model more suited for an independent test institute. More tests with third party papers and even third party inks.http://www.aardenburg-imaging.com/documents.html met vriendelijke groeten, Ernst Dinkla Try: http://groups.yahoo.com/group/Wide_Inkjet_Printers/ |  
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						| Peter_Corser 
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								|  | « Reply #11 on: October 01, 2009, 04:10:42 PM » |  | 
 
 Ernst
 Just for the record - I have an A3+ sized HP 8750 which is dye based with additional greys and a blue!
 
 Not passing any judgement, but when I get it right the prints can be superb.
 
 Peter
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						| Seth | 
								|  | « Reply #13 on: October 03, 2009, 04:46:45 PM » |  | 
 
 I would recommend Aardenburg as the better test institute. The method is better, the business model more suited for an independent test institute. More tests with third party papers and even third party inks.http://www.aardenburg-imaging.com/documents.htmlI agree.  I felt the move away from use of RIT testing to Wilhelm brought a very commercial aspect to the whole procedure.   |  
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						| hedwards 
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								|  | « Reply #14 on: October 04, 2009, 04:22:24 AM » |  | 
 
 I think though that the more important question ultimately is at what point one of the two technologies manages to outdo traditional print techniques. Admittedly I haven't been keeping up much with modern printing technology, but printing it yourself was never particularly cost effective. In general it always seemed like a waste of money when even the best printers that people would likely buy were barely keeping up with standard prints and for quite a bit of money.
 Prints when stored in a reasonable fashion last a really long time and with some of the new papers have stunning results. I've more or less fallen in love with some of the newer semi-translucent papers that I've had used for my prints.
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