Thanks for all the thoughts, and to update my issue:
(1) I realize that printable L*min will never be 0, although with a few combinations the ICC profiles indicate it should get down to about 3. With the Pro-100, Canon Luster, and Canon's ICC profile (the file is CNBBDUA0.ICM), the profile indicates L* min = 5, and that's close to a* = b* = 0 (actually about at b* = -1). At precisely a* = b* = 0, profile-indicated L* min is about 5.5. I'm basing this on observing the 3D gamut plot, rotated and enlarged, at
https://www.iccview.de/, a screen capture of which is the first attachment. But measured with the ColorMunki, a file printed in Qimage with rel. col. + BPC, the printed image patch of L* = a* = B* = 0 measures L* = 9.
Similarly, with the Pro-100, Canon Glossy II, and Canon's ICC profile (the file is CNBBDMA0.ICM), profile-indicated L* min = 5, but that's at about a* = 0, b* = -3. I had written to see the second attachment, but with it the board reported I'd exceeded my allocated 256 KB. At precisely a* = b* = 0, L* min is about 7. The printed patch of input values L* = a* = B* = 0 measures L* = 11.
So it's seems like there's an issue significantly beyond L* min not being neutral and/or being substantially above 0.
(2) I'm aware of, and use, the X-Rite software's ability to make special B&W profiles, and I intend to do more testing, partly around that. But to try to isolate variables and start with the most current, widely-used combinations, I decided to start with Canon's main papers and Canon's own profiles. My sense and limited testing indicates that X-Rite-built B&W profiles deliver slightly more neutral grays but no increase in Dmax / decrease in L* min.
(3) FWIW and as a comparison and control, I got two targets printed on Ilford RC silver halide paper, Pearl surface from Mpix (on which the target patch with input values L* = a* = B* = 0 measures L* = 7, a* = 1.0, b* = 2.4) and Glossy surface from Fromex (on which the target patch of L* = a* = B* = 0 measures L* = 8, a* = 0.8, b* = 2.2). Also, taking repeated measurements, over different days and after different calibrations, with the ColorMunki Photo shows that all measurements are within about +/- 0.3 of each other, and many are closer than that. In other words, I can't vouch for this spectrophotometer's accuracy (reporting the true value), but I can vouch for its precision (repeatedly reporting the same value).